DOI: https://doi.org/10.32515/2664-262X.2024.10(41).1.40-45
Study of STructure of Materials Which are Formed by Evaporation off Glass Arsenic-Selenium System for Further Use in the Automotive Industry
About the Authors
Liudmyla Tarandushka, Professor, Doctor in Technics (Doctor of Technic Sciences), Cherkasy State Technological University, Cherkasy, Ukraine, е-mail: tarandushkal@ukr.net, ORCID ID: 0000-0002-1410-9088
Victor Kovtunenko, Associate Professor, PhD in Physical and Mathematical (Candidate of Physical and Mathematical Science), Cherkasy State Technological University, Cherkasy, Ukraine, е-mail: kovtvics@ukr.net
Abstract
Thin films Ar-Se systev are widely usedin optoelectronics, in the production of microchips, there fore they are activelly used in modern automotive production. Improvement of methods of obtaining films with a renewable comprosition is an urgent problem.
The chemical composition of amorphous films sputter on changeable substrates at the thermal evaporation of arsenic(n)-selenium(100-n) glasses has been investigated and has been analyzed.
It was received that at the stage of glass evaporation in the interval less then 39 at % of arsenic the modifications of vapor phase over substraes changes for a time and it reaches by arsenic.
For glasses with n > 39 аt % the modifications enriches by selenium. These results have been analyzed? where the uneven character of application is connecting with the features of the chemical structure of arsenic(n)-selenium(n-k) glasses and their melts.
Keywords
amorphous films, pulsed thermal sputtering, simple thermal sputtering, chemical composition, FRPA, chalcogenides, condensate, evaporator, interference, X-ray spectral microanalysis
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References
1. K. White., B. Kumar., & K.Rai Amarendra, (1988) Effect of deposition rate on structure and properties of As2S3 films, Thin Solid Films. 161, 139 [in USA].
2. Ya.І. Dutchak. (1977). Renthenohrafia ridkyh metaliv. Vyscha shkola, Lviv. [in Ukrainian].
3. D. Ralf Steudel. (1975) Properties of Sulfur-Sulfur Bonds // Angewandte Chemie International Edition. 14, No. 10, 655. [in Germany].
4. V.S. Kovtunenko. (2016) Struktura dvo- ta tryatomovykh klasteriv parovoyi fazy materialiv systemy As–S [The structure of diatomic and triatomic clusters of the vapor phase of the materials of the system As–S] // Nanosystemy, nanomaterialy, nanotechnologiji: zb. nauk. pr. К.: RVV IMF. Т. 14, № 2. P. 221-234. [in Ukrainian].
5. Zakharov, V.P., & Gerasimenko, V.S. (1976). Structurnije osobennosti poluprovodnikov v amorphnom sostojanii. Akademiya nauk Ukrayinsʹkoyi RSR, Instytut problem materialoznavstva.. Kiyv, Naukova Dumka [in Ukrainian].
6. Popescu, A.A., Dolhyer, V.T., Vataman, I.I., Buzdugan, A.I., & Yndrychan, K.M. (1997). Molekuljarnij phazovij analiz tonkich plenok amorphnich AsxS100-x: Stekloobraznije poluprovodniki dlja optoelektroniki . Ed. House "Shtynytsa", Chisinau. P. 98-107 [in Moldova].
7. Chern, G.C., Zauks, J. & Mc.Ghie A.R. (1983). Spin-coated amorphous chalcogenide films: thermal properties. J. Applied Physics. V. 54. №8. P. 4596-4601. [in Ukrainian].
8. Martin, T.P. (1983). Arsenic sulfide clusters. Solid state communications. V.47, № 2. P.111-114. [in Belgium].
9. Popescu, A. (2002). Structure modelling of chalcogenide vitreous films by computational chemistry program. Moldavian J. of physical sciences. 2002 №2. P. 130-138. [in Moldova].
10. Ivanytskyi, V.P. (2008). Mekhanizmy formuvannia stokhastychno neodnoridnoi struktury amorfnykh khal'kohenidiv [Mechanisms of stochastically heterogeneous structure formation of amorphous chalcogenides]. Extended abstract of Doctor’s thesis [in Ukrainian].
Citations
1. K. White., B. Kumar., K.Rai Amarendra, Effect of deposition rate on structure and properties of As2S3 films, Thin Solid Films. 1988. Vol. 161. 139.
2. Дутчак Я.І. Рентгенографія рідких металів. Львів : Вища школа. 1977. 161 с.
3. D. Ralf Steudel. Properties of Sulfur-Sulfur Bonds . Angewandte Chemie International Edition. 14, No. 10, 655 (1975).
4. В.С. Ковтуненко. Структура дво- та триатомових кластерів парової фази матеріaлів системи As–S . Наносистеми, наноматеріали, нанотехнології: зб. наук. пр. К.: РВВ ІМФ, 2016. Т. 14, № 2. С. 221-234.
5. В.П. Захаров, В.С. Герасименко. Структурні особливості напівпровідників в аморфному стані : монографія . Академія наук Української РСР, Інститут проблем матеріалознавства. Київ: Наукова думка. 1976.
6. A.A. Попеску, В.Т. Долгер, I.I. Ватаман, A.I. Буздуган, K.M. Yndrychan. Молекулярний паровий аналіз тонких аморних плівок AsxS100-x: склоподібні напівпровідники для оптоелектроніки . Ed. House "Shtynytsa", Chisinau. 1997 . Р. 98-107
7. Chern G.C., Zauks J., McGhie A.R. Spin-coated amorphous chalcogenide films: thermal properties. J. Applied Physics. 1983. Vol. 54. № 8. P. 4596-4601.
8. Martin T.P. Arsenic sulfide clusters. Solid state communications, 1983. V.47, №2. P.111-114.
9. Popescu A. Structure modelling of chalcogenide vitreous films by computational chemistry program. Moldavian Journal of the Physical Sciences. № 2. 2002. P. 130-138.
10. Іваницький В.П. Механізми формування стохастичнонеоднорідної структури аморфних халькогенідів систем АIV-BV-XVI: автореф. дис... д-ра фіз.-мат. наук: 01.04.07 . Х. 2008. 34 с.
Copyright (c) 2024 Liudmyla Tarandushka, Victor Kovtunenko
Study of STructure of Materials Which are Formed by Evaporation off Glass Arsenic-Selenium System for Further Use in the Automotive Industry
About the Authors
Liudmyla Tarandushka, Professor, Doctor in Technics (Doctor of Technic Sciences), Cherkasy State Technological University, Cherkasy, Ukraine, е-mail: tarandushkal@ukr.net, ORCID ID: 0000-0002-1410-9088
Victor Kovtunenko, Associate Professor, PhD in Physical and Mathematical (Candidate of Physical and Mathematical Science), Cherkasy State Technological University, Cherkasy, Ukraine, е-mail: kovtvics@ukr.net
Abstract
Keywords
Full Text:
PDFReferences
1. K. White., B. Kumar., & K.Rai Amarendra, (1988) Effect of deposition rate on structure and properties of As2S3 films, Thin Solid Films. 161, 139 [in USA].
2. Ya.І. Dutchak. (1977). Renthenohrafia ridkyh metaliv. Vyscha shkola, Lviv. [in Ukrainian].
3. D. Ralf Steudel. (1975) Properties of Sulfur-Sulfur Bonds // Angewandte Chemie International Edition. 14, No. 10, 655. [in Germany].
4. V.S. Kovtunenko. (2016) Struktura dvo- ta tryatomovykh klasteriv parovoyi fazy materialiv systemy As–S [The structure of diatomic and triatomic clusters of the vapor phase of the materials of the system As–S] // Nanosystemy, nanomaterialy, nanotechnologiji: zb. nauk. pr. К.: RVV IMF. Т. 14, № 2. P. 221-234. [in Ukrainian].
5. Zakharov, V.P., & Gerasimenko, V.S. (1976). Structurnije osobennosti poluprovodnikov v amorphnom sostojanii. Akademiya nauk Ukrayinsʹkoyi RSR, Instytut problem materialoznavstva.. Kiyv, Naukova Dumka [in Ukrainian].
6. Popescu, A.A., Dolhyer, V.T., Vataman, I.I., Buzdugan, A.I., & Yndrychan, K.M. (1997). Molekuljarnij phazovij analiz tonkich plenok amorphnich AsxS100-x: Stekloobraznije poluprovodniki dlja optoelektroniki . Ed. House "Shtynytsa", Chisinau. P. 98-107 [in Moldova].
7. Chern, G.C., Zauks, J. & Mc.Ghie A.R. (1983). Spin-coated amorphous chalcogenide films: thermal properties. J. Applied Physics. V. 54. №8. P. 4596-4601. [in Ukrainian].
8. Martin, T.P. (1983). Arsenic sulfide clusters. Solid state communications. V.47, № 2. P.111-114. [in Belgium].
9. Popescu, A. (2002). Structure modelling of chalcogenide vitreous films by computational chemistry program. Moldavian J. of physical sciences. 2002 №2. P. 130-138. [in Moldova].
10. Ivanytskyi, V.P. (2008). Mekhanizmy formuvannia stokhastychno neodnoridnoi struktury amorfnykh khal'kohenidiv [Mechanisms of stochastically heterogeneous structure formation of amorphous chalcogenides]. Extended abstract of Doctor’s thesis [in Ukrainian].
Citations
1. K. White., B. Kumar., K.Rai Amarendra, Effect of deposition rate on structure and properties of As2S3 films, Thin Solid Films. 1988. Vol. 161. 139.
2. Дутчак Я.І. Рентгенографія рідких металів. Львів : Вища школа. 1977. 161 с.
3. D. Ralf Steudel. Properties of Sulfur-Sulfur Bonds . Angewandte Chemie International Edition. 14, No. 10, 655 (1975).
4. В.С. Ковтуненко. Структура дво- та триатомових кластерів парової фази матеріaлів системи As–S . Наносистеми, наноматеріали, нанотехнології: зб. наук. пр. К.: РВВ ІМФ, 2016. Т. 14, № 2. С. 221-234.
5. В.П. Захаров, В.С. Герасименко. Структурні особливості напівпровідників в аморфному стані : монографія . Академія наук Української РСР, Інститут проблем матеріалознавства. Київ: Наукова думка. 1976.
6. A.A. Попеску, В.Т. Долгер, I.I. Ватаман, A.I. Буздуган, K.M. Yndrychan. Молекулярний паровий аналіз тонких аморних плівок AsxS100-x: склоподібні напівпровідники для оптоелектроніки . Ed. House "Shtynytsa", Chisinau. 1997 . Р. 98-107
7. Chern G.C., Zauks J., McGhie A.R. Spin-coated amorphous chalcogenide films: thermal properties. J. Applied Physics. 1983. Vol. 54. № 8. P. 4596-4601.
8. Martin T.P. Arsenic sulfide clusters. Solid state communications, 1983. V.47, №2. P.111-114.
9. Popescu A. Structure modelling of chalcogenide vitreous films by computational chemistry program. Moldavian Journal of the Physical Sciences. № 2. 2002. P. 130-138.
10. Іваницький В.П. Механізми формування стохастичнонеоднорідної структури аморфних халькогенідів систем АIV-BV-XVI: автореф. дис... д-ра фіз.-мат. наук: 01.04.07 . Х. 2008. 34 с.