DOI: https://doi.org/10.32515/2664-262X.2022.5(36).2.58-63

Increasing the Abrasion Resistance of Aluminum Foundry Alloys AL-SI AK9 and AK12 Plasma-electrolytic Treatment

Mykhajlo Student, Іryna Pogrelyuk, Sergiy Markovych, Volodymyr Hvozdetskii, Khrystyna Zadopozna, Vladyslav Topchiy

Mykhajlo Student, Doctor in Technics (Doctor of Technics Sciences), Leading Researcher, Karpenko Physico-Mechanical Institute of NAS of Ukraine, e-mail: student.phmi@gmail.com, ORCID ID: 0000-0002-5992-5898

Іryna Pogrelyuk, Professor, Doctor in Technics (Doctor of Technics Sciences), Karpenko Physico-Mechanical Institute of NAS of Ukraine, Lviv, Ukraine, e-mail: irynapohrelyuk@gmail.com

Sergiy Markovych, Associate Professor, PhD in Technics (Candidate of Technics Sciences), Central Ukrainian National Technical University, Kropyvnytskyi, Ukraine, e-mail: marko60@ukr.net, ORCID ID: 0000-0003-1393-2360

Volodymyr Hvozdetskii, Senior Researcher, PhD in Technics (Candidate of Technics Sciences), Karpenko Physico-Mechanical Institute of NAS of Ukraine, e-mail: gvosdetcki@gmail.com

Khrystyna Zadorozhna, Senior Researcher, PhD in Technics (Candidate of Technics Sciences), Karpenko Physico-Mechanical Institute of NAS of Ukraine, e-mail: 880988@ukr.net

Vladyslav Topchiy, Associate Professor, PhD in Technics (Candidate of Technics Sciences), Lviv Polytechnic National University, Lviv, Ukraine, e-mail: vladyslav.i.topchii@lpnu.ua

Abstract

Aluminum casting alloys are used in machine-building, automobile, aviation, electrical and textile enterprises. However, aluminum alloys have low abrasive wear resistance, which significantly hinders their use in technological environments where abrasive particles are present. However, aluminum alloys have low abrasive wear resistance, which significantly hinders their use in technological environments where abrasive particles are present. The method of plasma electrolytic oxidation of plasma electrolyte treatment on aluminum alloys provides high hardness up to 2000 HV, low friction coefficient, high adhesion to the metal base, high environmental friendliness. However, this method does not allow the synthesis of oxide layers with high abrasive wear resistance on cast alloys - silumin. Plasma electrolyte treatment layers synthesized on the most widely used Al-Si foundry alloys have significant disadvantages: low rate of synthesis of the oxoceramic layer - 0.5 - 1 μm / min., Low thickness - up to 140 μm, low microhardness (700-1000 HV) and low abrasion resistance. Plasma electrolyte treatment layers were synthesized on the surface of 30x30 mm plates with a thickness of 4 mm from aluminum casting alloys AK-9 (9% Si) and AK-12 (12% Si) in electrolyte - 3 g / l KOH + 2 g / l Na2SiO3 (aqueous solution of liquid glass) without and with the addition to the electrolyte of 3 g / l of hydrogen peroxide H2O2, pulsed current at a frequency of 50 Hz in the cathode-anode mode at a ratio of currents (Ik / Ia) = 1 and a current density of 20 A / dm2. The thickness of the coatings after synthesis for 120 min was 120 -130 µm .. [4]. Metallographic studies were performed on a scanning electron microscope ZEISS EVO 40XVP with X-ray microanalysis system INCA Energy. The phase composition of the surface layers was investigated using a DRON-3M diffractometer in Cu-K radiation. Conclusions: 1. Plasma-electrolyte treatment of silumins AK-9 and AK-12 increases their microhardness up to 1000… 1300 HV, which causes an increase in their abrasive wear resistance by 14 ... 57 times. 2. Addition to the electrolyte of hydrogen peroxide H2O2 in the amount of 3% of the mass. increases the abrasive wear resistance of silumins after plasma electrolyte treatment by another 30 ... 70%. This is due to the increase in the content of oxide phases αAl2O3, γAl2O3 and the decrease in the content of the silicate phase of sillimanite - Al2O3 • SiO2 in the coating structure.

Keywords

plasma-electrolyte oxidation, aluminum cast alloys, oxide layers, wear resistance

Full Text:

PDF

References

1. Bazaluk, O., Dubei, O., Ropyak, L., Shovkoplias, M., Pryhorovska, T., Lozynskyi, V. (2022). Strategy of compatible use of jet and plunger pump with chrome parts in oil well . Energies, 15 (1), art. no. 83, DOI: 10.3390/en15010083 [in English].

2. Hutsaylyuka, V., Student, M., Zadorozhna, Kh., Student, O., Veselivska, H., Gvosdetskii, V.et al. (2020). Improvement of wear resistance of aluminum alloy by HVOF method . Journal of Materials Research and Technology. Vol. 9, Iss. 6. P. 16367–16377, //doi.org/10.1016/j.jmrt.2020.11.102 . [in English].

3. Student M., Gvozdetsky V., Student O., Prentkovskis O., Maruschak P.,Olenyuk, O., Titova, L. (2019). The Effect of Increasing the Air Flow Pressure on the Properties of Coatings during the Arc Spraying of Cored Wires . Strojnicky Casopisthis link is disabled, 69(4), pp. 133–146, DOI:10.2478/scjme-2019-0048 [in English].

4. Michaela Remešová, Serhii Tkachenko, Daniel Kvarda, Ivana Ročňáková, Bernhard Gollas, Melita Menelaou ewt al. (2020). Effects of anodizing conditions and the addition of Al2O3 /PTFE particles on the microstructure aluminium alloy . Applied Surface Science Volume 513, 30 May 2020, 145780 //doi.org/10.1016/j.apsusc.2020.145780 [in English].

5. Xiaopeng Lu , Marta Mohedano, Carsten Blawert, Endzhe Matykina, Raul Arrabal, Karl Ulrich Kainer, et al. (2016). Plasma electrolytic oxidation coatings with particle additions – A review . Surface and Coatings TechnologyVolume 307, Part C, 15 December 2016, Pages 1165-1182 //doi.org/10.1016/j.surfcoat.2016.08.055 [in English].

6. Rogov, A.B., Lyu, H., Matthews, A., Yerokhin, A. (2020), AC plasma electrolytic oxidation of additively manufactured and cast AlSi12 alloys, Surf. Coat. Technol. 399 126116, https://doi.org/10.1016/j.surfcoat.2020.126116 [in English].

7. Li K., Li W., Zhang G., Zhu W., Zheng F., Zhang D., Wang M. (2019). Effects of Si phase refinement on the plasma electrolytic oxidation of eutectic Al-Si alloy, J. Alloys Compd. 790, pp. 650–656 [in English].

GOST Style Citations

  • Bazaluk, O., Dubei, O., Ropyak, L., Shovkoplias, M., Pryhorovska, T., Lozynskyi, V. (2022) Strategy of compatible use of jet and plunger pump with chrome parts in oil well . Energies, 15 (1), art. no. 83, DOI: 10.3390/en15010083
  • Improvement of wear resistance of aluminum alloy by HVOF method. V. Hutsaylyuka, M. Student, Kh. Zadorozhna, O. Student, H. Veselivska, V. Gvosdetskii, P.Maruschak, H.Pokhmurska . Journal of Materials Research and Technology. 2020. Vol. 9, Iss. 6. P. 16367–16377, doi.org/10.1016/j.jmrt.2020.11.102 .
  • The Effect of Increasing the Air Flow Pressure on the Properties of Coatings during the Arc Spraying of Cored Wires / Student M., Gvozdetsky V., Student O., Prentkovskis O., Maruschak P.,Olenyuk, O., Titova, L. Strojnicky Casopisthis link is disabled, 2019, 69(4), pp. 133–146, DOI: 10.2478/scjme-2019-0048
  • Effects of anodizing conditions and the addition of Al2O3/PTFE particles on the microstructure aluminium alloy / Michaela Remešová, Serhii Tkachenko, Daniel Kvarda, Ivana Ročňáková, Bernhard Gollas, Melita Menelaou, Ladislav Čelko, Jozef Kaise . Applied Surface Science, Vol. 513, 30 May 2020, 145780. doi.org/10.1016/j.apsusc.2020.145780
  • Plasma electrolytic oxidation coatings with particle additions – A review / Xiaopeng Lu , Marta Mohedano, Carsten Blawert, Endzhe Matykina, Raul Arrabal, Karl Ulrich Kainer, Mikhail L. Zheludkevich. Surface and Coatings Technology. Vol. 307, Part C, 15 December 2016, P. 1165-1182. doi.org/10.1016/j.surfcoat.2016.08.055
  • A.B. Rogov, H. Lyu, A. Matthews, A. Yerokhin, AC plasma electrolytic oxidation of additively manufactured and cast AlSi12 alloys, Surf. Coat. Technol. 399 (2020), 126116, https://doi.org/10.1016/j.surfcoat.2020.126116.
  • K. Li, W. Li, G. Zhang, W. Zhu, F. Zheng, D. Zhang, M. Wang, Effects of Si phase refinement on the plasma electrolytic oxidation of eutectic Al-Si alloy, J. Alloys Compd. 790 (2019) 650–656, https://doi.org/10.1016/j.jallcom.2019.03.217.
  • Copyright (c) 2022 Mykhajlo Student, Іryna Pogrelyuk, Sergiy Markovych, Volodymyr Hvozdetskii, Khrystyna Zadopozna, Vladyslav Topchiy